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26 March, 08:07

Carbon-14 is a radioactive isotope which decays with a half-life of 5730 years. what is the first-order rate constant for its decay, in units of years-1?

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  1. 26 March, 10:25
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    In chemical equilibrium, radioactive decay occurs because of unstability due to the high neutron-to-proton ratio. Through time, the radioactive element is converted to a new element. This radioactive decay undergoes first order reaction. Its equation is in the form of

    A = A₀e^ (-kt), where A is the amount of the element after time t, A₀ is the original amount of element at t=0 and k is the rate constant.

    Half-life is the amount of time for A to be 1/2 of A₀. Modifying the equation during half time, we let A=1/2 A₀. Then.

    1/2 A₀ = A₀e^ (-kt)

    1/2 = e^ (-k (5730))

    k = 0.000121

    Thus, the first-order rate constant is equal to 0.000121 per year.
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