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14 June, 15:21

What mass of oxygen would be produced upon thermal decomposition of 25 g of potassium chlorate (kclo3) ? the molecular weight (mw) of potassium chlorate is 122.5 g/mol?

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  1. 14 June, 17:09
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    The formula for potassium chlorate is: 2KClO₃ → 2KCl + 3O₂

    If moles = mass : molar mass

    then moles of KClO₃ = 25 g : [ (39 * 1) + (35.5 * 1) + (16 * 3) ] g/mol

    = 25 g : (122.5 g) g/mol

    = 0.2041 mol

    Now the mole ratio of KClO₃ : O₂ is 2 : 3

    ∴ if moles of KClO₃ = 0.2041 mol

    then moles of O₂ = (0.2041 mol : 2) * 3

    = 0.3061 mol

    Now since mass = moles * molar mass

    ∴ the mass of oxygen produced = 0.3061 mol * (16 * 2) g/mol

    = 9.796 g

    ∴ the grams of oxygen gas produced when 25 grams of potassium chlorate is decomposed is ~ 9.80 g.
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