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31 January, 10:18

Be sure to answer all parts. find the molar solubility of bacro4 (ksp = 2.1 * 10-10) in (a) pure water * 10 m (b) 1.6 * 10-3 m na2cro4 * 10 m

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  1. 31 January, 12:32
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    A) in pure water:

    by using ICE table:

    According to the reaction equation:

    BaCrO4 (s) → Ba^2 + (aq) + CrO4^2 - (aq)

    initial 0 0

    change + X + X

    Equ X X

    when Ksp = [Ba^2+][CrO4^2-]

    by substitution:

    2.1 x 10^-10 = X * X

    ∴X = √2.1 x 10*-10

    ∴X = 1.4 x 10^-5

    ∴ the solubility = X = 1.4 X 10^-5

    B) In 1.6 x 10^-3 m Na2CrO4

    by using ICE table:

    According to the reaction equation:

    BaCrO4 (s) → Ba^2 + (aq) + CrO4^2 - (aq)

    initial 0 0.0016

    Change + X + X

    Equ X X+0.0016

    when Ksp = [Ba^2+][CrO4^2-]

    by substitution:

    2.1 x 10^-10 = X * (X+0.0016) by solving for X

    ∴ X = 1.3 x 10^-7

    ∴ solubility = X = 1.3 x 10^-7
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