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11 November, 13:25

In the hydrogenation of ethylene using a nickel catalyst, the initial concentration of ethylene is 1.70 mol⋅L-1 and its rate constant (k) is 0.0013 mol⋅L-1⋅s-1. Determine the rate of reaction if it follows a zero-order reaction mechanism.

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  1. 11 November, 14:53
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    Rate = rate constant = 0.0013 mol⋅L-1⋅s-1

    Explanation:

    The rate law for a chemical reaction is an equation that relates the reaction rate with the concentrations or partial pressures of the reactants. For the general reaction;

    aA+bB→C

    with no intermediate steps in its reaction mechanism, meaning that it is an elementary reaction, the rate law is given by:

    r=k[A]^x[B]^y

    In this equation, [A] and [B] express the concentrations of A and B, respectively, in units of moles per liter. and k = rate constant

    A zero-order reaction has a constant rate that is independent of the concentration of the reactant (s); the rate law is simply rate=k. For a zero-order reaction, increasing the concentration of the reacting species will not speed up the rate of the reaction.

    The rate law for a zero-order reaction is rate = k.

    This means the rate of the reaction is give as;

    Rate = rate constant = 0.0013 mol⋅L-1⋅s-1
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