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23 January, 21:10

Consider the reaction IO-4 (aq) + 2H2O (l) ⇌H4IO-6 (aq); Kc=3.5*10-2 If you start with 26.0 mL of a 0.904 M solution of NaIO4, and then dilute it with water to 500.0 mL, what is the concentration of H4IO-6 at equilibrium?

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  1. 23 January, 23:28
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    0.744 M

    Explanation:

    IO⁻⁴ (aq) + 2H₂O (l) ⇌ H₄IO⁻⁶ (aq)

    Kc = 3.5*10⁻² = [H₄IO⁻⁶] / [IO⁻⁴]

    First let's calculate the new concentration of IO⁻⁴ at equilibrium:

    0.904 M * 26.0 mL / 500.0 mL = 0.047 M = [IO⁻⁴]

    Now we can calculate [H₄IO⁻⁶] using the formula for Kc:

    3.5*10⁻² = [H₄IO⁻⁶] / [IO⁻⁴]

    3.5*10⁻² = [H₄IO⁻⁶] / 0.047 M

    [H₄IO⁻⁶] = 0.744 M
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