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2 November, 06:10

The p K a of acetic acid is 4.76, and the p K a of trichloroacetic acid, which is used to remove warts, is 0.7. Calculate the dissociation constant of each acid. Which is the stronger acid?

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  1. 2 November, 09:54
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    CH3COOH: Ka = 1.74 E-5

    CCL3COOH: Ka = 0.1995

    ⇒ K CCl3COOH >> K CH3COOH ∧ pKCCl3COOH < pKCH3COOH; the higher pKa the extent of the dissociation is less; therefore CCl3COOH is a stronger acid than CH3COOH

    Explanation:

    CH3COOH:

    pKa = 4.76 = - Log Ka

    ⇒ Ka = 1.74 E-5

    CCl3COOH:

    ∴ pKa = 0,7 = - log Ka

    ⇒ Ka = 0.1995
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