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9 April, 08:34

What is the approximate pH of a 0.06 M solution of CH3COOH (given that Ka = 1.78 x 10-5) ? A. 1 B. 3 C. 6 D. 7 E. 9

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  1. 9 April, 11:54
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    the answer is 3 which corresponds to B. 3

    Explanation:

    CH3COOH + H2O ⇄ CH3COO⁻ + H3O⁺

    Since CH3COOH is a weak acid, it does not dissociate completely. Therefore an "x" value is being ionized to make the product.

    At equilibrium:

    [CH3COOH]=0.06 - x (because the "x" value have been ionized)

    [CH3COO-] = x

    [H3O+] = x

    We know that Ka = [CH3COO-][H3O+]/[CH3COOH] from the formula

    at equilibrium, Ka = (x*x) / (0.06-x)

    because of the small Ka value, we can make a mathematic assumption 0.06 is really higher than "x"

    Ka = (x^2) / 0.06

    x^2 = (1.78x10^5) (0.06)

    x = 0.0010334 = [H3O+]

    pH = - log of [H3O+]

    pH = - log (0.0010334) = 3.0
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