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14 February, 12:14

The value of ka for nitrous acid (hno2) at 25 ∘c is 4.5*10-4. what is the value of δg at 25 ∘c when [h+] = 5.9*10-2m, [no2-] = 6.3*10-4m, and [hno2] = 0.21m? be sure to express your answer in units of kj in the box below. answers without units will not be given credit.

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  1. 14 February, 14:42
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    To get the value of ΔG we need to get first the value of ΔG°:

    when ΔG° = - R*T*㏑K

    when R is constant in KJ = 0.00831 KJ

    T is the temperature in Kelvin = 25+273 = 298 K

    and K is the equilibrium constant = 4.5 x 10^-4

    so by substitution:

    ∴ ΔG° = - 0.00831 * 298 K * ㏑4.5 x 10^-4

    = - 19 KJ

    then, we can now get the value of ΔG when:

    ΔG = ΔG° - RT*㏑[HNO2]/[H+][NO2]

    when ΔG° = - 19 KJ

    and R is constant in KJ = 0.00831

    and T is the temperature in Kelvin = 298 K

    and [HNO2] = 0.21 m & [H+] = 5.9 x 10^-2 & [NO2-] = 6.3 x 10^-4 m

    so, by substitution:

    ΔG = - 19 KJ - 0.00831 * 298K * ㏑ (0.21/5.9x10^-2*6.3 x10^-4)

    = - 40
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