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29 March, 04:02

Integrate the expression α=1/V (∂V/∂T) P assuming that α is independent of pressure. By doing so, obtain an expression for V as a function of T and α at constant P.

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  1. 29 March, 04:27
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    V (T) = Peᵅᵀ

    Step-by-step explanation:

    α = 1/V (dV/dT) P

    Rearranging and separating variables

    (α/P) dT = (1/V) dV

    Taking the integrals of both sides

    ∫ (α/P) dT = ∫ (1/V) dV

    αT/P = ln V + ln C, C a constant of integration

    Taking the exponent of both sides

    exp (αT/P) = exp (ln V + ln C)

    exp (αT/P) = exp (ln V) X exp (ln C)

    CV=exp (αT/P)

    Since Pressure is constant, exp (P) = Constant, say K.

    V (T) = Peᵅᵀ where Pressure = K/C
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