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30 July, 11:50

Reacting with water in an acidic solution at a particular temperature, compound A decomposes into compounds B and C according to the law of uninhibited decay. An initial amount of 0.30 M of compound A decomposes to 0.25 M in 30 minutes. How much of compound A will remain after 3 hours? How long will it take until 0.10 M of compound A remains?

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  1. 30 July, 12:26
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    Step-by-step explanation:

    We would apply the formula,

    A (t) = Aoe^kt

    Where

    Ao represents the initial concentration of compound A.

    k represents the rate of decomposition.

    t represents the decomposition time.

    A (t) represents the concentration after t hours.

    From the information given

    Ao = 0.30 M

    t = 30 minutes = 0.5 hour

    A (0.5) = 0.25 M

    Therefore,

    0.25 = 0.3e^0.5k

    0.25/0.3 = e^0.5k

    0.833 = e^0.5k

    Taking ln of both sides, it becomes

    ln0.833 = ln e^0.5k = 0.5k

    k = - 0.1827/0.5

    k = - 0.3654

    The expression becomes

    A (t) = 0.35e^-0.3654t

    1) When t = 3 hours,

    A (3) = 0.35e^-0.3654 * 3

    A (3) = 0.35e^ - 1.0962

    A (3) = 0.117M

    2) When A = 0.1, then

    0.1 = 0.35e^-0.3654 * t

    0.1/0.35 = e^-0.3654t

    0.2857 = e^-0.3654t

    Taking ln of both sides, it becomes

    Ln 0.2857 = - 0.3654t

    - 1.2528 = - 0.3654t

    t = - 1.2528 / - 0.3654

    t = 3.43 hours
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