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15 February, 09:01

The constant pressure molar heat capacity, C_{p, m}C p, m , of nitrogen gas, N_2N 2 , is 29.125/text{ J K}^{-1}/text{ mol}^{-1}29.125 J K - 1 mol - 1 at 298/text{ K}298 K. Calculate the change in the internal energy when 20/text{ mol}20 mol of nitrogen gas at 298/text{ K}298 K is heated so that its temperature increases by 15.0^{/circ}/text{C}15.0 ∘ C. You may assume constant heat capacity over the temperature range.

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  1. 15 February, 11:34
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    Constant pressure molar heat capacity Cp = 29.125 J / K. mol

    If Cv be constant volume molar heat capacity

    Cp - Cv = R

    Cv = Cp - R

    = 29.125 - 8.314 J

    = 20.811 J

    change in internal energy = n x Cv x Δ T

    n is number of moles, Cv is molar heat capacity at constant volume, Δ T is change in temperature

    Putting the values

    = 20 x 20.811 x 15

    = 6243.3 J.
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