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22 August, 07:56

Calculate the ph of a solution prepared by mixing 40.0 ml of a 0.02 m hcl solution with 200.0 ml of 0.20 m hcn solution. assume volumes to be additive ka for hcn=1.0x10^-10

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  1. 22 August, 10:13
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    First, we have to get moles of each HCl & HCN

    moles of HCl = volume * molarity

    = 0.04 L * 0.02 M = 0.0008 moles

    moles of HCN = volume * molarity

    = 0.2 L * 0.2 M = 0.04moles

    ∴Total moles = 0.04 + 0.0008 = 0.0408 moles

    and the total volume = 0.04 L + 0.2 L = 0.24 L

    ∴the total concentration = total moles / total volume

    = 0.0408 moles / 0.24 L

    = 0.17 M

    when we assume [H+] = X

    ∴ Ka = X^2 / (0.17-X)

    by substitution

    ∴ 1 x 10^-10 = X^2 / (0.17 - X)

    ∴X = 4.12 x 10^-6

    ∴[H+] = 4.12 x 10^-6

    ∴PH = - ㏒ (4.12 x 10^-6)

    = 5.4
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