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10 April, 08:18

Identify reagents necessary to convert cyclohexane into 1,3-cylohexadiene: notice that the starting material has no leaving groups and cannot simply be treated with a strong base. you must first introduce functionality into the starting material.

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  1. 10 April, 08:54
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    1,3-cylohexadiene i synthesized starting from cyclohexane in following 4 steps.

    1) Free Radical Substitution Rxn: Halogenation of cyclohexane in the presence of UV yield chlorocyclohexane.

    2) Elimination Rxn: Dehydrohalogenation of chlorocyclohexane yields cyclohexene.

    3) Halogenation of Cyclohexene (Electrophillic Addition Rxn) gives 1,2-dihalocyclohexane.

    4) Elemination Rxn: When dibromocyclohexane is treated with KOH and heated it gives 1,3-cyclohexadiene as shown below,
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