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14 April, 19:42

If an aqueous solution containing M2 + ions electrolyzed by a current of 3.00 A for 60.0 min., resulting in 3.66 g of solid M produced at a cathode during this time, what is the likely identity of the element M

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  1. 14 April, 20:01
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    According to Faraday's Law,

    W = I t e / F

    Where,

    W = Amount deposited = 3.66 g

    I = Current = 3 A

    t = Time = 60 min = 3600 s

    e = Chemical equivalence

    F = Faraday's Constant = 96500

    Solving for e,

    e = F W / I t

    Putting Values,

    e = (96500*3.66) : (3 * 3600)

    e = 32.7

    As we know,

    e = M / 2

    solving for M,

    M = e * 2

    Putting value of e,

    M = 32.7 * 2

    M = 65.4

    M = Zinc
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