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25 June, 07:11

A buffer is prepared by adding 100 mL of 0.50 M sodium hydroxide to 100 mL of 0.75 M propanoic acid. Is this a buffer solution, and if so, what is its pH?

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  1. 25 June, 10:56
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    The answer: is yes, It is a buffer solution.

    first, we need to get moles of sodium hydroxide and propanoic acid:

    moles NaOH = molarity * volume

    = 0.5M * 0.1 L = 0.05 moles

    moles propanoic acid = molarity * volume

    = 0.75 M * 0.1 L = 0.075 moles

    [NaOH] at equilibrium = 0.05 m

    [propanoic acid ] at equilibrium = 0.075 - 0.05 = 0.025 m

    when Pka for propanoic acid (given) = 4.89

    so by substitution:

    ∴PH = Pka + ㏒[NaOH]/[propanoic acid ]

    ∴ PH = 4.89 + ㏒ 0.05 / 0.025

    = 5.19
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