A compound has a pka of 7.4. to 100 ml of a 1.0 m solution of this compound at ph 8.0 is added 30 ml of 1.0 m hydrochloric acid. the resulting solution is ph:

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Chemistry

Haley Cowan

10 September, 17:48

A compound has a pka of 7.4. to 100 ml of a 1.0 m solution of this compound at ph 8.0 is added 30 ml of 1.0 m hydrochloric acid. the resulting solution is ph:

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Asa Walter · Answer 1

Using the Henderson-Hasselbalch equation on the solution before HCl addition: pH = pKa + log ([A-]/[HA]) 8.0 = 7.4 + log ([A-]/[HA]); [A-]/[HA] = 4.0. (equation 1) Also, 0.1 L * 1.0 mol/L = 0.1 moles total of the compound. Therefore, [A-] + [HA] = 0.1 (equation 2) Solving the simultaneous equations 1 and 2 gives: A - = 0.08 moles AH = 0.02 moles Adding strong acid reduces A - and increases AH by the same amount. 0.03 L * 1 mol/L = 0.03 moles HCl will be added, soA - = 0.08 - 0.03 = 0.05 moles AH = 0.02 + 0.03 = 0.05 moles Therefore, after HCl addition, [A-]/[HA] = 0.05 / 0.05 = 1.0 Resubstituting into the Henderson-Hasselbalch equation: pH = 7.4 + log (1.0) = 7.4, the final pH.