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27 February, 13:34

10. If a reaction has ΔS = - 100 J/K and is spontaneous, what must be true of the surroundings? A) ΔSsurroundings > 100 J/K B) ΔSsurroundings > - 100 J/K C) ΔSsurroundings = 100 J/KD) ΔSsurroundings < - 100 J/K E) ΔSsurroundings < 100 J/K

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  1. 27 February, 15:30
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    Answer : The correct option is, (C) ΔS (surroundings) = 100 J/K

    Explanation:

    As we know that:

    ΔS (total) = ΔS (system) + ΔS (surroundings)

    When the reaction is spontaneous ΔS (total) > 0, that means positive value.

    When the reaction is non-spontaneous ΔS (total) < 0, that means negative value.

    As we are given that:

    ΔS (system) = - 100 J/K (for spontaneous reaction)

    Thus, the ΔS (surroundings) must be greater than ΔS (system) that means positive value.

    So, ΔS (surroundings) = 100 J/K

    Hence, the correct option is, (C) ΔS (surroundings) = 100 J/K
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