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3 July, 05:40

The vapor pressure of pure water at 25 °C is 23.8 torr. Determine the vapor pressure (torr) of water at 25 °C above a solution prepared by dissolving 35 g of urea (a nonvolatile, non-electrolyte, molar mass = 60.0 g/mol) in 75 g of water.

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  1. 3 July, 06:58
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    Vapor pressure of solution = 20.8 Torr

    Explanation:

    This is about vapor pressure lowering

    ΔP = P°. Xm

    ΔP states the difference between vapor pressure of pure solvent and vapor pressure from solution.

    P° is the vapor pressure of pure solvent.

    Xm means mole fraction (mol of solute / mol of solute + mol of solvent)

    Let's determine the mol of solute

    35 g / 60 g/mol = 0.583 mol of urea

    Let's determine the mol of solvent

    75 g / 18 g/mol = 4.167 mol of water

    Total moles = 0.583 + 4.167 = 4.75

    Mole fraction of solute → 0.583 / 4.75 = 0.123

    Let's replace the data in the formula:

    23.8Torr - Vapor pressure of solution = 23.8 Torr. 0.123

    Vapor pressure of solution = - (23.8 Torr. 0.123 - 23.8 Torr)

    Vapor pressure of solution = 20.8 Torr
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