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5 October, 14:20

The energy required for self-diffusion is 1.6eV. At 100 degrees C, 1% of the atoms have the energy required for self-diffusion. How many of the atoms would have the energy required for self-diffusion at 120 degrees C?

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  1. 5 October, 15:35
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    12.6% of the atoms

    Explanation:

    We know that:

    In (D2/D1) = [Qd/R] [ (1/T1) - (1/T2) ]

    where Qd is activation energy for diffusion

    T is temperature

    Given that

    Qd = activation energy for diffusion = 1.6 eV

    R = 8.62 x 10-5 eV/K

    D1 = 1 %

    D2 = ?

    T1 = 100°C = 100 + 273 K = 373 K

    T2 = 120°C = 120 + 273 K = 393 K

    Then,

    Calculation:

    In (D2/D1) = [Qd/R] [ (1/T1) ] - (1/T2) ]

    In (D2/1) = [1.6 eV / 8.62 x 10⁻⁵ eV/K] [ (1/373) ] - (1/393) ]

    On solving,

    D2 = 12.6 %

    Therefore,

    12.6% of the atoms have the energy required for self-diffusion at 120°C.
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