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18 April, 10:09

Nitric acid, a major industrial and laboratory acid, is produced commercially by the multi-step Ostwald process, which begins with the oxidation of ammonia: Step 1: NH3 (g) + O2 (g) LaTeX: / longrightarrow⟶ NO (g) + H2O (l) Step 2: NO (g) + O2 (g) LaTeX: / longrightarrow⟶ NO2 (g) Step 3: NO2 (g) + H2O (l) LaTeX: / longrightarrow⟶ HNO3 (l) + NO (g) Assuming 100% yield in each step, what mass (in kg) of ammonia must be used to produce 7.839 kg of nitric acid. Enter to 3 decimal places. Are the equations balanced?

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  1. 18 April, 11:05
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    Answer: 3.178 Kg of ammonia must be used to produce 7.839 kg of nitric acid and The equations are not balanced. Explanation: Ostwald process is a multi-step for manufacturing Nitric Acid. First, We must check if our equations are balanced or not, by checking the amount of each element before and after the arrow. Step 1: NH3 (g) + O2 (g) ⟶ NO (g) + H2O (l) Step 2: NO (g) + O2 (g) ⟶ NO2 (g) Step 3: NO2 (g) + H2O (l) ⟶ HNO3 (l) + NO (g) For example in Step 1, the amount of Hydrogen atoms are different on both sides. On left side we can count 3 hydrogen atoms while on the right side we can count only 2 hydrogen atoms. In the Step 2, the amount of Oxygen atoms are different on both sides too. On the Left side we can count 3 oxygen atoms while on the right side we can count only 2 oxygen atoms and in step 3 the amount of Nitrogen atoms are different on both sides too. On the left side we can count 1 nitrogen atom while on the right side we can count 2 nitrogen atoms. So, Let's balance equations by inspection, just adding coefficients to each compound, until the amount of atoms are equal on both sides. Step 1: 4NH3 (g) + 5O2 (g) ⟶4 NO (g) + 6 H2O (l) Step 2: 2NO (g) + O2 (g) ⟶ 2NO2 (g) Step 3: 3NO2 (g) + H2O (l) ⟶ 2HNO3 (l) + NO (g) Second we gather the information what we are going to use in our calculations. Final Mass of HNO3 = 7,839Kg and Molecular Weigth = 63,01g/mol NH3 Molecular Weight = 17,031 g/mol Third we start discoverying the amount of NH3 that reacted completed to generate 7,839Kg of HNO3, using the giving equation and its respective molecular weights. 7,839Kg of HNO3 x 1000g / 1Kg x 1mol HNO3 / 63,01g HNO3 x 3mol NO2 / 2 mol HNO3 x 2 mol NO / 2 mol NO2 x 4 mol NH3/4 mol NO x 17,031g NH3/1 mol NH3 x 1 Kg / 1000g = 3,178 Kg NH3 The amount of NH3 that is required to produce 7,839 Kg of HNO3 is 3,178 Kg NH3
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