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27 October, 11:27

Balance the chemical equation using the vector equation approach. If possible, use exact arithmetic or rational format for calculations in balancing the following chemical reaction: PbN6+CrMn2O8→Pb3O4+Cr2O3+MnO2+NO

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  1. 27 October, 11:53
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    15 PbN6 + 44 CrMn2O8 = 5 Pb3O4 + 22 Cr2O3 + 88 MnO2 + 90 NO

    Explanation:

    Every time you need to balance a chemical equation, you need to end up with the same amount of products that the initial substances.

    PbN6+CrMn2O8→Pb3O4+Cr2O3+MnO2+NO

    Start analyzing the pairs to balance.

    Let's start with the ones to get oxidate (the electrons will be with the products)

    The Pb starts alone and as a product, you have Pb 3. You balance this semi equation like this.

    3PbN → Pb3O4 + 2e-

    With the Cr, the same happens.

    2CrMn2O8 → Cr2O3 + 2e-

    With N you have to balance the product because you start with N6.

    PbN6 → 6NO + 14e-

    And then, the one that gets reduced Mn

    CrMn2O + 6e - → 2MnO2

    Now, combine the oxidate and reduce pairs

    3PbN6 → Pb3O4 + 18NO + 44e-

    and

    2CrMn2O8 + 10e - → Cr2O3 + 4MnO2

    Now, equilibrate charges.

    3PbN6 → Pb3O4 + 18NO + 44e - + 44H+

    2CrMn2O8 + 10e - + 10H + → Cr2O3 + 4MnO2

    and oxygen.

    3PbN6 + 22H2O → Pb3O4 + 18NO + 44e - + 44H+

    2CrMn2O8 + 10e - + 10H + → Cr2O3 + 4MnO2 + 5H2O

    Now, you can count and see the one that oxidated have to be multiplied by 22 (extra electrons in reduction) and the one reducing by 5 (extra electrons in oxidation)

    Then, group and simplify the waters and you'll find that the balanced equation is

    15 PbN6 + 44 CrMn2O8 = 5 Pb3O4 + 22 Cr2O3 + 88 MnO2 + 90 NO
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