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24 February, 09:55

20 Liters of a mixture of N2 gas and CH4 gas was made up with a pressure of 700. Mm Hg and a temperature of 300. C. If the partial pressure of N2 gas was 250. Mm Hg, how many grams of CH4 were added to the mixture?

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  1. 24 February, 10:46
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    4.04g of CH₄ are in the mixture

    Explanation:

    In a mixture of gases, the total pressure is equal to partial pressure of each gas in the mixture.

    In the problem, total pressure is 700mmHg and there are just 2 gases (N₂ ans CH₄) where the partial pressure of N₂ is 250mmHg. Thus, pressure of CH₄ is:

    700mm Hg - 250mm Hg = 450mmHg. In atm:

    450 mmHg ₓ (1 atm / 760mm Hg) = 0.5921 atm

    Using PV = nRT

    Where P is pressure (0.5921atm), V is volume (20L), R is gas constant (0.082atmL/molK), T is absolute temperature (300°C + 273.15 = 573.15K), it is possible to obtain moles - n - of the gas, thus:

    PV / RT = n

    0.5921atm*20L / 0.082atmL/molK*573.15K = n

    0.252 moles CH₄ = n

    As molar mass of CH₄ is 16.04 g/mol:

    0.252 moles CH₄ * (16.04g / 1mol) = 4.04g of CH₄ are in the mixture
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