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21 August, 07:32

what is the relationship between electronegativity and bond type? Put another way, how could you predict whether a compound would be ionic or covalent if given a list of the elements' electronegativities?

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  1. 21 August, 11:28
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    The greater the difference in electronegativity (ΔEN) between two atoms, the greater the degree in ionic character in the bond.

    If you have a bond between atoms A and B (A-B),

    ΔEN = |EN_A - EN_B|

    The rules for the type of bond are:

    • If ΔEN < 0.5, the bond is nonpolar covalent

    • If 0.5 ≤ΔEN < 1.7, the bond is polar covalent

    • If ΔEN ≥ 1.7, the bond is ionic

    Examples:

    C-H: ΔEN = |2.55 - 2.20| = 0.35; nonpolar covalent

    C-F: ΔEN = |2.55 - 3.98| = 1.43; polar covalent

    Na-F: ΔEN = |0.93 - 3.98| = 3.05; ionic
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