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6 July, 11:05

c. Lead crystallizes in a face-centered cubic structure with a density of 11.34 g/cm3. Polonium crystallizes in a simple cubic structure with a density of 9.3 g/cm3. Explain why lead has a greater density than polonium even though polonium atoms are heavier, and smaller than lead atoms.

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  1. 6 July, 12:48
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    Because of their differences in their crystal systems, lead is more densely packed.

    Explanation:

    In a face-centered cubic structure, there's a total of 4 atoms per unit cell (1/8 * 8 atoms in the corners, plus 1/2 * 6 atoms in each of the faces). This also means that in each cube, each atom is surrounded by 12 other atoms.

    While in a simple cubic structure, there's a total of only one atom per unit cell (1/8 * 8 atoms in the corners).

    In other words, if we have one lead crystal and one polonium crystal of the same size, there's a greater number of lead atoms than of polonium.
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