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19 June, 17:42

A buffer contains 0.010 mol of lactic acid (pka = 3.86) and 0.050 mol sodium lactate per liter of aqueous solution.

a. Calculate the ph of this buffer.

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  1. 19 June, 21:21
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    The given buffer solution contains lactic acid and sodium lactate

    i. e. CH3CH (OH) COOH/CH3CH (OH) COONa

    Lactic acid is therefore a monoprotic acid with pKa = 3.86

    Concentration of Lactic acid = 0.010 mol/L = 0.010 M

    Concentration of sodium lactate = 0.050 mol/L = 0.050 M

    Based on Henderson-Hasselbalch equation, the pH of the buffer is given as:

    pH = pKa + log[salt]/[acid]

    pH = pKa + log [CH3CH (OH) COONa]/[CH3CH (OH) COOH]

    pH = 3.86 + log[0.050/0.010] = 4.56
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