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30 September, 11:39

A mixture of pure agcl and pure agbr is found to contain 60.94% ag by mass. what are the mass percents of cl and br in the mixture?

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  1. 30 September, 13:09
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    First step is to calculate the mass of Ag in each compound separately:

    From the periodic table:

    molar mass of Ag is 107.87 gm

    molar mass of Cl is 35.45 gm

    molar mass of Br is 79.9 gm

    For AgCl, mass % of Ag = [107.87/143.32] x 100 = 75.26%

    For AgBr, mass % of Ag = [107.87/187.77] x 100 = 57.45 %

    Second step is to calculate the mass % of each compound in the mixture:

    Assume mass % of AgCl is y and that of AgBr is (1-y) as the total percentage is 100% or 1

    0.6094 = 0.7526 y + 0.5745 (1-y)

    y = 0.8716

    This means that the mixture is almost 87% AgCl and 13% AgBr

    The mass % of chlorine and bromine together is (100%-60.94%) which is 39.06%

    mass % of chlorine = (1-0.6094) (0.8716) x 100 = 34.044%

    mass % of bromine = 39.04 - 34.044 = 5.056%
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