The activation energy of a certain reaction is 37.2 kJ/mol. At 20 ∘C, the rate constant is 0.0130 s-1. At what temperature would this reaction go twice as fast? Express your answer numerically in degrees Celsius

Question

Physics

Alana Mcmillan

26 February, 10:02

The activation energy of a certain reaction is 37.2 kJ/mol. At 20 ∘C, the rate constant is 0.0130 s-1. At what temperature would this reaction go twice as fast? Express your answer numerically in degrees Celsius

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Answers (1)

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Dolce · Answer 1

Answer: At 34°c

Explanation:

Using The Arrhenius Equation:

k = Ae - Ea/RT

k represents rate constant

A represents frequency factor and is constant

R represents gas constant which is = 8.31J/K/mol

Ea represents the activation energy

T represents the absolute temperature.

By taking the natural log of both sides,

ln k = ln A - Ea/RT

Reactions at temperatures T1 and T2 can be written as;

ln k1 = ln A - Ea/RT1

ln k2 = ln A - Ea/RT2

Therefore,

ln (k1/k2) = - Ea/RT1 + Ea/RT2

Since k2=2k1 this becomes:

ln (1/2) = Ea/R*[1/T2 - 1/T1]

Theefore,

-0.693 = 37.2 x 10^3/8.31 * [ 1/T2 - 1/293]

1/T2 - 1/293 = - 1.55 x 10^-4

1/T2 = - 1.55 x 10^-4 + 34.13x 10^-4

1/T2 = 32.58 x 10^-4

Therefore T2 = 307K

T2 = 307 - 273 = 34 °c