Which are the first particles to evaporate from a liquid?

Explained below:

Explanation:

Evaporation occurs when a liquid substance changes into a gas by heating the water. The first particles to evaporate from a liquid are those with the highest kinetic energy. The aggregate amount of this kinetic energy transfer is named as thermal energy which occurs only when there is a differential in the water molecule's temperature. Liquid water that becomes water vapor takes a parcel of heat with it in a process called evaporative cooling.