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15 January, 22:45

If the atomic radius of lead is 0.175 nm, calculate the volume of its unit cell in cubic meters.

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  1. 16 January, 00:18
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    Before any calculations, we need to determine first the crystal structure of the lead metal. From literature, the lead metal assumes an FCC structure. So, it would have 4 atoms per units cell where the three atoms is the sum of all the portion of an atoms in each face of the cell and the 1 atom is the sum of all the portion of the corner atoms. The volume of the unit cell is equal to the edge length raise to the power three or V = a^3. The edge length can be calculated from the radius of the atoms by the pythagorean theorem. We do as follows:

    V = a^3

    a^2 + a^2 = (4r) ^2

    2a^2 = (4r) ^2

    a = 2r

    V = (2r) ^3

    V = 16r^3

    V = 16 (0.175x10^-9) ^3

    V = 1.21 x 10^-28 m^3
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