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4 May, 08:29

Determine the value of the equilibrium constant, Kgoal, for the reaction N2 (g) + H2O (g) ⇌NO (g) + 12N2H4 (g), Kgoal=? by making use of the following information: 1. N2 (g) + O2 (g) ⇌2NO (g), K1 = 4.10*10-31 2. N2 (g) + 2H2 (g) ⇌N2H4 (g), K2 = 7.40*10-26 3. 2H2O (g) ⇌2H2 (g) + O2 (g), K3 = 1.06*10-10 Express your answer numerically.

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  1. 4 May, 11:58
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    K = 1.79x10⁻³³

    Explanation:

    Using Hess's law, it is possible to fin K of a reaction by the algebraic sum of another related reactions.

    In the reactions:

    1. N2 (g) + O2 (g) ⇌ 2NO (g), K1 = 4.10*10-31 2.

    2. N2 (g) + 2H2 (g) ⇌ N2H4 (g), K2 = 7.40*10-26

    3. 2H2O (g) ⇌2H2 (g) + O2 (g), K3 = 1.06*10-10

    The sum of 1/2 (1) + 1/2 (2) produce:

    N2 (g) + 1/2O2 (g) + H2 (g) ⇌ 1/2N2H4 (g) + NO (g)

    And K' = √4.1x10⁻³¹*√7.4x10⁻²⁶ = 1.74x10⁻²⁸

    Now, this reaction + 1/2 (3):

    N2 (g) + H2O (g) ⇌ NO (g) + 1/2N2H4 (g)

    And K of reaction is:

    1.74x10⁻²⁸*√1.06x10⁻¹⁰ = 1.79x10⁻³³
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